Preorganized frustrated Lewis pairs.
نویسندگان
چکیده
Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu(2)PCH(2)BPh(2) with H(2), CO(2), and isocyanates and supported computationally.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 134 1 شماره
صفحات -
تاریخ انتشار 2012